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The abatement of carbon dioxide and pollutant emissions on motorbike spark-ignition (SI) engines is a challenging task, considering the small size, the low cost and the high power-to-weight ratio required by the market for such powertrain. In this context, the passive pre-chamber (PPC) technology is an attractive solution. The combustion duration can be reduced by igniting the air-fuel mixture inside a small volume connected to the cylinder, unfolding the way to high engine efficiencies without penalization of the peak performance. Moreover, no injectors are needed inside the PPC, guaranteeing a cheap and fast retrofitting of the existing fleet. In this work, a 3D computational fluid dynamics (CFD) investigation is carried out over an experimental configuration of motorbike SI engine, operated at fixed operating conditions with both traditional and PPC configurations.

Gasoline, direct injection engines represent one of the most widely adopted powertrain for passenger cars. However, further development efforts are necessary to meet the future fuel consumption and emission standards imposing an efficiency increase and a reduction of particulate matter emissions. Within this context, computational fluid dynamics is nowadays a consolidated tool to support engine design; this work is focused on the development of a set of CFD models for the prediction of combustion in modern GDI engines. The one-equation Weller model coupled with a zero-dimensional approach to handle initial flame kernel growth was applied to predict flame propagation. To account for mixture fraction fluctuations which might lead to the presence of soot precursor species, burned gas chemical composition is computed using tabulated kinetics with a presumed probability density function.

To improve the combustion and emission characteristics of the large-bore marine engines, the spray is usually designed as an inter-spray impingement to promote the fuel-air mixing process, which implies frequent droplet collisions. Properly describing the collision dynamics of liquid droplets has been of interest in the field of spray modeling for marine engine applications. In this context, this work attempts to develop an accurate and efficient methodology for modeling impinging sprays under engine-like conditions. Experimental validations in terms of spray penetration and morphology are initially carried out at different operating conditions considering the parametric variations of ambient temperature and pressure, where the measurements are performed on a large-scale constant volume chamber with two symmetrical injectors.

Predictive combustion models are useful tools towards the development of clean and efficient engines operating with alternative fuels. This work intends to validate two different combustion models on compression-ignition engines fueled with Dimethyl Ether. Both approaches give a detailed characterization of the combustion kinetics, but they substantially differ in how the interaction between fluid-dynamics and chemistry is treated. The first one is single-flamelet Representative Interactive Flamelet, which considers turbulence-kinetic interaction but cannot correctly describe the stabilization of the flame. The second, named Tabulated Well Mixed, correctly accounts for local flow and mixture conditions but does not consider interaction between turbulence and chemistry. An experimental campaign was carried out on a heavy-duty truck engine running on DME at a constant load considering trade-off of EGR and SOI.

A comprehensive model for sprays emerging from high pressure swirl injectors for GDI engine application has been developed. The primary and secondary atomization mechanism as well as the evaporation process both in standard and superheated conditions are taken into account. The spray modelling after the injection is based on the Liquid Instability Sheet Atomization (LISA) approach, modified to correctly predict the liquid sheet thickness at the breakup length. The effect of different values of the superheat degree on evaporation and impact on the spray distribution and fuel-air mixing is analyzed. Comparisons with experimental data show good agreements under atmospheric conditions and with different superheated degrees, while some discrepancies occur under higher ambient pressures.

Using natural gas in an internal combustion engine (ICE) is emerging as a promising way to improve thermal efficiency and reduce exhaust emissions. In the development of such engine platforms, computational fluid dynamics (CFD) plays a fundamental role in the optimization of geometries and operating parameters. One of the most relevant issues in the simulation of direct injection (DI) gaseous processes is the accurate prediction of the gas jet evolution. The simulation of the injection process for a gaseous fuel does not require complex modeling, nevertheless properly describing high-pressure gas jets remains a challenging task. At the exit of the nozzle, the injected gas is under-expanded, the flow becomes supersonic and shocks occur due to compressibility effects. These phenomena lead to challenging computational requirements resulting from high grid resolution and low computational time-steps.

Emissions from CI engines fueled with dimethyl ether (DME) were discussed in this paper. Thanks to its high content of fuel oxygen, DME combustion is virtually soot free. This characteristic of DME combustion indicates that the particulate filter will not be needed in the aftertreatment system for engines fueled with DME. NOx emissions from a CI engine fueled with DME can meet the US 2007 regulation with a high EGR rate. Because 49% more fuel mass must be delivered in each DME injection than the corresponding diesel-fuel injection, and the DME injection pressure is lower than 500 bar under the current fuel-system technology, the DME injection duration is generally longer than that of diesel-fuel injection. This is unfavorable to further NOx reduction. A multiple-injection strategy with timing for the primary injection determined by the cylinder temperature was proposed.

A key strategy to improving the real-world fuel consumption and emissions of medium and heavy duty vehicles is the hybridization of these applications. Unlike the passenger vehicle market, medium and heavy duty applications are typically comprised of a range of components from a variety of manufacturers. The vocational market diversity and size places considerable demand on fuel efficiency and emission compliance. Medium and heavy duty applications have the ability to be successfully hybridized in ways that are not currently, or would not be practical within a passenger vehicle. This would also drive greater truck and bus vertical integration of the hybrid components. However, medium and heavy duty manufacturers have been prevented from certifying a full vehicle level platform due to the current engine only certification requirements.

Gasoline is a complex fuel. Many of the constituents of gasoline that are beneficial for the internal combustion engine (ICE) are expected to be challenging for on-board reformers in fuel-cell vehicles. To address these issues, the autothermal reforming of gasoline and individual components of gasoline has been investigated. The results indicate that aromatic components require higher temperatures and longer contact times to reform than paraffinic components. Napthenic components require higher temperatures to reform, but can be reformed at higher space velocities than paraffinic components. The effects of sulfur are dependent on the catalyst. These results suggest that further evolution of gasoline could reduce the demands on the reformer and provide a better fuel for a fuel-cell vehicle.

At the current stage of engine technology, diesel engines typically require diesel particulate filter (DPF) systems to meet recent particulate emissions standards. To assure the performance and reliability of DPF systems, profound understanding of filtration and regeneration mechanisms is required. Among extensive efforts for developing advanced DPF systems, the development of effective thermal management strategies, which control the thermal runaway taking place in oxidation of an excess amount of soot deposit in DPF, is quite challenging. This difficulty stems mainly from lack of sufficient knowledge and understanding about DPF regeneration mechanisms, which need detailed information about oxidation of diesel particulate matter (PM). Therefore, this work carried out a series of oxidation experiments of diesel particulates collected from a DPF on a diesel engine, and evaluated the oxidation rates of the samples using a thermo-gravimetric analyzer (TGA).

Detailed characteristics of morphology, nanostructures, and sizes were analyzed for particulate matter (PM) emissions from low-temperature combustion (LTC) modes of a single-cylinder, light-duty diesel engine. The LTC engines have been widely studied in an effort to achieve high combustion efficiency and low exhaust emissions. Recent reports indicate that the number of nucleation mode particles increased in a broad engine operating range, which implies a negative impact on future PM emissions regulations in terms of the nanoparticle number. However, the size measurement of solid carbon particles by commercial instruments is indeed controversial due to the contribution of volatile organics to small nanoparticles. In this work, an LTC engine was operated with various biofuel blends, such as blends (B20) of soy bean oil (soy methyl ester, SME20) and palm oil (palm methyl ester, PME20), as well as an ultra-low-sulfur diesel fuel.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.

Early in 2007 President Bush announced in his State of the Union Address a plan to off-set 20% of gasoline with alternative fuels in the next ten years. Ethanol, due to its excellent fuel properties for example, high octane number, renewable character, etc., appears to be a favorable alternative fuel from an engine perspective. Replacing gasoline with ethanol without any additional measures results in unacceptable disadvantages mainly in terms of vehicle range. This paper summarizes combustion studies performed with gasoline as well as blends of gasoline and ethanol. These tests were performed on a modern, 4-cylinder spark ignition engine with direct fuel injection and exhaust gas recirculation. To evaluate the influence of blending on the combustion behavior the engine was operated on the base gasoline calibration. Cylinder pressure data taken during the testing allowed for detailed analysis of rates of heat release and combustion stability.

Because of their high efficiency and low emissions, fuel-cell vehicles are undergoing extensive research and development. When considering the introduction of advanced vehicles, a complete well-to-wheel evaluation must be performed to determine the potential impact of a technology on carbon dioxide and Green House Gases (GHGs) emissions. Several modeling tools developed by Argonne National Laboratory (ANL) were used to evaluate the impact of advanced powertrain configurations. The Powertrain System Analysis Toolkit (PSAT) transient vehicle simulation software was used with a variety of fuel cell system models derived from the General Computational Toolkit (GCtool) for pump-to-wheel (PTW) analysis, and GREET (Green house gases, Regulated Emissions and Energy use in Transportation) was used for well-to-pump (WTP) analysis. This paper compares advanced propulsion technologies on a well-to-wheel energy basis by using current technology for conventional, hybrid and fuel cell technologies.

Gas-to-Liquids (GTL) is a liquid diesel fuel produced from natural gas, which may have certain attributes different from conventional ultra low sulfur diesel (ULSD). In this investigation, GTL, ULSD, and their blends of 20% and 50% GTL in ULSD were tested in an older Mercedes C Class (MY1999, Euro 2) and a newer Opel Astra (MY2006, Euro 4) diesel vehicle to evaluate the performance in terms of fuel consumption and emissions. Each vehicle was pre-conditioned on-road with one tank full of test fuel before actual testing in a chassis dynamometer facility. Both vehicles were calibrated for European emission standards and operation, and they were not re-calibrated for the fuel tests at Argonne National Laboratory (ANL). In the two-vehicle EPA FTP-75, US06, and Highway drive-cycle tests, the emissions of carbon dioxide on a per-mile basis (g/mi) from all GTL-containing fuels were significantly lower than those from the ULSD.

SunDiesel fuel is a biomass-to-liquid (BTL) fuel that may have certain attributes different from conventional diesel. In this investigation, 100% SunDiesel was tested both in a Mercedes A-Class (MY1999) diesel vehicle and a single-cylinder heavy-duty compression-ignition direct-injection engine. The SunDiesel's emissions and fuel consumption were significantly better than conventional diesel fuel, especially in nitrogen oxides (NOx) reduction. In the vehicle U.S. Environmental Protection Agency (EPA), Federal Test Procedure 75 (FTP-75), and New European Drive Cycle (NEDC) tests, the carbon dioxide emissions on a mile basis (g/mile) from SunDiesel fuel were almost 10% lower than the conventional diesel fuel. Similarly, in the single-cylinder engine steady-state tests, the reductions in brake specific NOx, carbon monoxide (CO), and particulate matter (PM) are equally significant. Combustion analysis, though not conclusive, indicates that there are differences deserving further research.

It is well known that in-nozzle flow behavior can significantly influence the near-nozzle spray formation and mixing that in turn affect engine performance and emissions. This in-nozzle flow behavior can, in turn, be significantly influenced by fuel properties. The goal of this study is to characterize the behavior of two different fuels, namely, a straight-run naphtha that has an anti-knock index of 58 (denoted as “Full-Range Naphtha”) and n-dodecane, in a simulated multi-hole common-rail diesel fuel injector. Simulations were carried out using a fully compressible multi-phase flow representation based on the mixture model assumption with the Volume of Fluid method. Our previous studies have shown that the characteristics of internal and near-nozzle flow are strongly related to needle motion in both the along- and off-axis directions.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

In response to the stipulations of the Energy Policy and Conservation Act and the global momentum toward carbon mitigation, there has been a pronounced tightening of fuel economy standards for manufacturers. This stricter regulation is coupled with an accelerated transition to electric vehicles, catalyzed by advances in electrification technology and a decline in battery cost. Improvements in the fuel economy of medium- and heavy-duty vehicles through electrification are particularly noteworthy. Estimating the magnitude of fuel economy improvements that result from technological advances in these vehicles is key to effective policymaking. In this research, we generated vehicle models based on assumptions regarding advanced transportation component technologies and powertrains to estimate potential vehicle-level fuel savings. We also developed a systematic approach to evaluating a vehicle’s fuel economy by calibrating the size of the components to satisfy performance requirements.

To properly compare and contrast the environmental performance of one vehicle technology against another, it is necessary to consider their production, operation, and end-of-life fates. Since 1995, Argonne’s GREET® life cycle analysis model (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) has been annually updated to model and refine the latest developments in fuels and materials production, as well as vehicle operational and composition characteristics. Updated cradle-to-grave life cycle analysis results from the model’s latest release are described for a wide variety of fuel and powertrain options for U.S. light-duty and medium/heavy-duty vehicles. Light-duty vehicles include a passenger car, sports utility vehicle (SUV), and pick-up truck, while medium/heavy-duty vehicles include a Class 6 pickup-and-delivery truck, Class 8 day-cab (regional) truck, and Class 8 sleeper-cab (long-haul) truck.